Preheat oven to 175°C.
In a bowl combine chocolate and butter and melt it in MW or a double boiler.
Keep it aside.
Add vinegar, vanilla and milk and set it aside for 10 minutes.
In a large bowl, combine together flour, baking powder, cocoa powder and sugar.
Add the milk mix and chocolate mix and whisk to combine.
Use a spatula to fold the batter.
Line a 7"square cake tin with parchment and grease it well.
Let the paper hang outside the tin which will help you to remove the brownies later.
Bake for 35 - 40 minutes until a toothpick comes out clean.
Refrigerate for 2 hours before removing the brownie from the pan.
Trim the sides and slice it into 16 equal squares with a bread knife.
Reheat the slices just before serving.